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GCD Regenerative Thermal Oxidisers

Description

Regenerative Thermal Oxidation (RTO) Technology is the fastest growing segment of the air pollution control equipment supply market. RTO technology has emerged as the preferred technology for treating Hazardous Air Pollutants (HAP) emissions for waste gas streams with low concentrations and large volumes.

Its popularity stems from its ability to achieve very high VOC destruction with no by-product disposal and at reasonable operating costs.

Regenerative Thermal Oxidisers (RTO) are distinguished by their ability to achieve high heat recovery efficiencies, often as high as 95%. This is a significant advantage for high volume, contaminated air streams with low organic concentrations and no process waste heat requirements.
 
Table 1 below compares the operating costs of an RTO with those of a thermal oxidiser without heat recovery, and a thermal oxidiser with recuperative heat recovery, all of which are treating a 25,000 scfm waste gas stream containing 50ppm of acetone. The fuel cost savings with the RTO are very significant

 

TABLE 1 :     FUEL COST COMPARISON

 

  Annual Fuel Cost
Thermal Oxidiser Without Heat Recovery 
 
1,046,000
Thermal Oxidiser With Recuperative Heat Recovery (70% Recovery) 
 
345,000
Regenerative Thermal Oxidiser with 95% Heat Recovery 
 
95,000
Basis for calculations: 
  • 25,000 scfm Fume Flow (11.2 Nm3/s) 
  • Negligible Heat From VOC 
  • 1400oF Oxidiser Temperature (760oC) 
  • Natural Gas @ USD 3.00/MM BTU 
  • (ie USD 3.16/Gj h) 
  • 8400 Operating Hours Per Year
 

Table 2 below shows relative costs between capital and operating costs for RTO, thermal oxidiser with recuperator, and basic thermal oxidiser without waste heat recovery.
 

TABLE 2:      RELATIVE COSTS

 

Oxidiser Type % Heat Recovery Capital Cost Operating Cost
Basic 
 

 

 
18 
 
Recuperative 
 
70 
 
2.75 
 
5.5 
 
Regenerative 
 
95 
 
3.85 
 

 

Source, Technical papers: * Economics of heat recovery in the Thermal Oxidation of Waste.

RTO technology emerged in the mid 1980's. Until recently, RTO designs incorporated at least three beds packed with a heat transfer medium. However, many suppliers are now offering two bed designs. Two bed designs offer significant savings in capital costs with only a minimal reduction in unit performance.
 
The USA Clean Air Act (CM) amendments of 1990 require that the EPA establish Maximum Achievable Control Standards (MACT) for major sources of Hazardous Air Pollutants (HAP) emissions. The EPA has identified 174 major industry categories which are subject to MACT standards. Some MACT standards have already been promulgated while others are imminent.

A list of 189 specific chemical compounds have been identified as HAPs. Nineteen (19) of the 189 HAPs account for nearly 75 percent of the total air toxics emissions. Most of these 19 compounds can be controlled effectively with thermal oxidation technology.

The EPA classifies a major source as one which emits greater than 10 tons/yr of any one HAP or 25 tons/yr of a combination of HAPs. HAP emissions are determined from a combination of concentration and waste gas flow. For example, a waste gas stream at a flow rate of 5,000 scfm must contain 50ppm of acetone to be classified as a major source. However, if the flow rate is 25,000 scfm, a concentration of only 10ppm would qualify this waste gas as a major source.

Previous to MACT standards, waste gases containing low concentrations of VOC were not regulated. However, waste gas streams that contain low concentrations may now be regulated if the volume of gas is high.

Most of the newly regulated streams are air streams contaminated with one or more HAPs. Examples are painting operations in the aerospace and automotive industries, drying operations in the wood products industry, and coating operations in the semiconductor industry.

In the USA the EPA estimates that the aerospace industry alone emits more than 208,000 tons/yr of Hazardous Air Pollutants plus an additional 145,000 tons/yr of Volatile Organic Compounds (VOCs). VOCs will also be regulated in areas in which ozone levels exceed National Ambient Air Quality  Standards (NMQS). Implementation of recently enacted MACT standards for the aerospace industry are projected to cost the industry between $16.5 and $25 billion.